Transition metal complex catalyzed carboxylation reactions with CO2
Transition metal complex catalyzed carboxylation reactions with CO2
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DOI：
10.1016/j.ccr.2014.09.002
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发表时间：
2015-06
影响因子：
20.6
通讯作者：
Dingyi Yu;S. Teong;Yugen Zhang
中科院分区：
文献类型：
--
作者：
Dingyi Yu;S. Teong;Yugen Zhang
过渡金属配合物在CO2催化羧化反应中起着关键作用。各种金属络合物催化体系已被开发用于不同底物的羧化，为绿色有机合成提供了通用的方法。本文综述了过渡金属配合物催化的CO2羰基化反应的研究进展。本文按不同过渡金属和不同官能团的底物进行了综述。反应机理和金属催化剂的作用也将被讨论。
Transition metal complexes play a key role in catalytic carboxylation reactions with CO2. Various metal complex catalytic systems have been developed for the carboxylation of different substrates that provide versatile methodologies for green organic synthesis. This review summarizes recent developments of CO2carboxylation reactions with Csingle bondC bond formation catalyzed by transition metal complexes. The contents in this review are arranged based on various transition metals and substrates of various functional groups. The reaction mechanisms and the role of metal catalysts will also be discussed.