Solvent-dependent nuclearity, geometry and catalytic activity of [(SPhos)Pd(Ph)Cl] 2
Solvent-dependent nuclearity, geometry and catalytic activity of [(SPhos)Pd(Ph)Cl] 2
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[(SPhos)Pd(Ph)Cl] 2 的溶剂依赖性核性、几何形状和催化活性
DOI：
10.1039/c7dt01019b
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发表时间：
2017
影响因子：
4
通讯作者：
Brazier J
中科院分区：
文献类型：
--
作者：
Brazier J
钯配合物[（SPhos）Pd（Ph）Cl]2在固体和溶液状态下的核性和结构被重新使用扩展X射线吸收精细结构（EXAFS）光谱、NMR光谱、质谱、DFT计算和捕获实验的组合。在甲苯、1，4-二氧六环和DMF中考察了该配合物对氯苯与正己胺偶联反应的催化活性，发现该配合物在甲苯、1，4-二氧六环和DMF中有不同的失活行为。
The nuclearity and structures of the palladium complex [(SPhos)Pd(Ph)Cl]2 in the solid and solution states are revisited using a combination of Extended X-ray Absorption Fine Structure (EXAFS) spectroscopy, NMR spectroscopy, mass spectrometry, DFT calculations and trapping experiments. The complex was tested for its catalytic activity in the coupling reaction between chlorobenzene and n-hexylamine, where different deactivation behaviours were observed in toluene, 1,4-dioxane and DMF.