Aggregation in solution of neutral half-sandwich Ru(II) precatalysts for transfer hydrogenation
Aggregation in solution of neutral half-sandwich Ru(II) precatalysts for transfer hydrogenation
复制标题
用于转移加氢的中性半夹心 Ru(II) 预催化剂溶液中的聚集
DOI：
10.1039/b415560b
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发表时间：
2005
影响因子：
3.3
通讯作者：
A. Macchioni
中科院分区：
文献类型：
--
作者：
D. Zuccaccia;E. Clot;A. Macchioni
扩散核磁共振测量和ONIOM （B3PW91:UFF）计算表明，氨基酰胺和酸半夹层Ru（II）转移加氢预催化剂在几种溶剂（包括催化反应所用的溶剂异丙醇）中具有形成二聚体甚至更大聚集体的显著趋势。
Diffusion NMR measurements and ONIOM (B3PW91:UFF) calculations show that amino amidate and acidate half-sandwich Ru(II) precatalysts for transfer hydrogenation have a remarkable tendency to form dimers and even larger aggregates in several solvents, including isopropanol, that is, the solvent used in the catalysis reaction.