2-Dimensional molecular wiring based on toroidal delocalization of hexaarylbenzene

2-Dimensional molecular wiring based on toroidal delocalization of hexaarylbenzene
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DOI:
10.1039/c0cc00128g
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发表时间:
2010-01-01
影响因子:
4.9
通讯作者:
Akita, Munetaka
Akita, Munetaka
中科院分区:
化学2区
文献类型:
--
作者:
Tanaka, Yuya;Koike, Takashi;Akita, Munetaka

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制备了一系列具有两个外环噻吩取代基的六芳基苯,发现两个金属中心通过在外环芳基之间的环向离域相互通信。
A series of hexaarylbenzenes having two peripheral thienyliron substituents has been prepared, and it is revealed that the two metal centres communicate with each other through toroidal delocalization among the peripheral aromatic groups.