Precise Manipulation of Temperature-Driven Chirality Switching of Molecular Universal Joints through Solvent Mixing
Precise Manipulation of Temperature-Driven Chirality Switching of Molecular Universal Joints through Solvent Mixing
复制标题
通过溶剂混合精确操控分子万向节的温度驱动手性切换
DOI：
10.1002/chem.201902676
复制
发表时间：
2019-08-28
影响因子：
4.3
通讯作者：
Yang, Cheng
中科院分区：
文献类型：
--
作者：
Fan, Chunying;Yao, Jiabin;Yang, Cheng
通过混合两种互溶的有机溶剂精确地控制了三柱芳烃分子万向接头（MUJ）的温度驱动手性转换，在每种溶剂中手性反转都是不可逆的.溶剂混合极大地改变了MUJ的反转温度，并且温度驱动的手性切换方向可以通过混合两种溶剂的比例来严格控制。更多信息可以在W.吴角，加-地Yang等人（DOI：10.1002/chem.201902676）。
Temperature-driven chirality switching of three pillar[5]arene-based molecular universal joints (MUJs) was precisely manipulated by mixing two miscible organic solvents, in each of which chirality inversion is not accomplishable. Solvent mixing drastically varied the inversion temperature of MUJs, and the temperature-driven chirality switching direction could be critically controlled by mixing the ratios of two solvents. More information can be found in the Full Paper by W. Wu, C. Yang, et al. (DOI: 10.1002/chem.201902676).