New diketo-pyrrolo-pyrrole (DPP) sensitizer containing a furan moiety for efficient and stable dye-sensitized solar cells

New diketo-pyrrolo-pyrrole (DPP) sensitizer containing a furan moiety for efficient and stable dye-sensitized solar cells
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含有呋喃部分的新型二酮吡咯并吡咯(DPP)敏化剂,用于高效稳定的染料敏化太阳能电池

DOI:
10.1016/j.dyepig.2011.09.009
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发表时间:
2012-03
期刊:
影响因子:
4.5
通讯作者:
Hua, Jianli
Hua, Jianli
中科院分区:
材料科学2区
文献类型:
--
作者:
Wu, Wenjun;Kong, Cong;Long, Yitao;Hua, Jianli

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以二酮基吡咯并吡咯为基础,通过简单的合成路线和低成本的方法,合成了一种新型的无金属有机敏化剂,该敏化剂以呋喃为间隔基,可用于染料敏化太阳能电池。为了比较,还合成了两种相应的带有苯和噻吩间隔基的染料。在优化的DSSC测试条件的基础上,含呋喃的敏化剂在模拟全太阳光照射下显示出5.65%的显著太阳能转换效率(η)(Jsc= 15.96 mA cm−2,Voc= 541 mV,ff = 0.65)。染料还在无溶剂离子液体电解质装置中进行了测试,并且在全阳光下进行了超过2000 h的装置稳定性。含呋喃结构的敏化剂具有良好的稳定性和更好的光伏性能,功率转换效率高达4.41%。
A new metal-free organic sensitizer containing a furan moiety as the π-spacer based on the diketo-pyrrolo-pyrrole unit was synthesized through simple synthetic routes and with low cost for the application of dye-sensitized solar cells. Two corresponding dyes with benzene and thiophene spacers were also synthesized for the purpose of comparison. On the basis of optimized DSSC test conditions, the sensitizer containing the furan shows prominent solar energy conversion efficiency (η) of 5.65% (Jsc= 15.96 mA cm−2, Voc= 541 mV, ff = 0.65) under simulated full sunlight irradiation. The dyes were also tested in a solvent-free ionic liquid electrolyte devices and the stability of devices was performed over 2000 h at full sunlight. The sensitizer containing the furan moiety exhibited good stability and better photovoltaic performance of up to 4.41% power conversion efficiency.
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