Methanol-Promoted Borylation of Arylamines: A Simple and Green Synthetic Method to Arylboronic Acids and Arylboronates
Methanol-Promoted Borylation of Arylamines: A Simple and Green Synthetic Method to Arylboronic Acids and Arylboronates
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甲醇促进的芳胺硼化：一种简单、绿色的芳基硼酸和芳基硼酸酯合成方法
DOI：
10.1055/s-0033-1339118
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发表时间：
2014-05
期刊：
影响因子：
2
通讯作者：
Xiao Jianliang
中科院分区：
文献类型：
--
作者：
Zhao Cong-Jun;Xue Dong;Jia Zhi-Hui;Wang Chao;Xiao Jianliang
摘要以亚硝酸钠和盐酸为重氮化剂，甲醇为催化剂，芳基胺经SN2Ar途径进行Sandmeyer硼化反应，为芳基硼酸和芳基硼酸酯的合成提供了一种简单、绿色的合成方法。
Abstract A Sandmeyer borylation of arylamines via a SN2Ar pathway promoted by methanol with sodium nitrite and hydrochloric acid as diazotization agent has been developed, which provide a simple and green synthetic method to arylboronic acids and arylboronates.