Organic electrode materials and carbon/small-sulfur composites for affordable, lightweight and sustainable batteries
Organic electrode materials and carbon/small-sulfur composites for affordable, lightweight and sustainable batteries
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用于经济、轻质和可持续电池的有机电极材料和碳/小硫复合材料
DOI：
10.1039/d3cc02652c
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发表时间：
2023
影响因子：
4.9
通讯作者：
Luo, Chao
中科院分区：
文献类型：
--
作者：
Luo, Chao
氧化还原活性有机/聚合物材料和碳/小硫复合材料具有成本低、资源丰富、碳足迹低、结构可调等优点，是开发价格低廉、重量轻、可持续发展电池的理想电极材料。这篇专题文章综述了有机电池和基于有机/聚合物/硫材料的锂S电池(LSB)的研究重点，以实现下一代可持续储能。对碱性离子电池、多价金属电池、全固态电池和氧化还原液流电池中的有机电极材料进行了深入的讨论。还介绍了在高质量负载和贫电解液条件下实际应用的最先进的LSB。讨论了有机电池和LSB面临的挑战、反应机理、策略、途径和发展趋势，为合理的结构设计和性能优化提供指导。这篇专题文章将有助于价格实惠、重量轻和可持续的电池的开发和商业化。
Redox-active organic/polymeric materials and carbon/small-sulfur composites are promising electrode materials for developing affordable, lightweight, and sustainable batteries because of their low cost, abundance, low carbon footprint, and flexible structural tunability. This feature article summarized the key aspects of the research related to organic batteries and Li–S batteries (LSBs) based on organic/polymeric/sulfur materials for next-generation sustainable energy storage. An in-depth discussion for organic electrode materials in alkali-ion, multivalent metal, all-solid-state, and redox flow batteries is provided. State-of-the-art LSBs under high mass loading and lean electrolyte conditions for practical applications is also covered. The challenges, reaction mechanisms, strategies, approaches, and developments of organic batteries and LSBs are discussed to offer guidance for rational structure design and performance optimization. This feature article will contribute to the development and commercialization of affordable, lightweight, and sustainable batteries.