Large Nonclassical Electrostriction in (Y, Nb)‐Stabilized δ‐Bi2O3
Large Nonclassical Electrostriction in (Y, Nb)‐Stabilized δ‐Bi2O3
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DOI：
10.1002/adfm.201503942
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发表时间：
2016-02
影响因子：
19
通讯作者：
N. Yavo;Alaric D. Smith;O. Yeheskel;Sydney Cohen;R. Korobko;E. Wachtel;P. Slater;I. Lubomirsky
中科院分区：
文献类型：
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作者：
N. Yavo;Alaric D. Smith;O. Yeheskel;Sydney Cohen;R. Korobko;E. Wachtel;P. Slater;I. Lubomirsky
Classical electrostriction, describing a second‐order electromechanical response of insulating solids, scales with elastic compliance, S, and inversely with dielectric susceptibility, ε. This behavior, first noted 20 years ago by Robert Newnham, is shown to apply to a wide range of electrostrictors including polymers, glasses, crystalline linear dielectrics, and relaxor ferroelectrics. Electrostriction in fluorite ceramics of (Y, Nb)‐stabilized δ‐Bi2O3 is examined with 16%–23% vacant oxygen sites. Given the values of compliance and dielectric susceptibility, the electrostriction coefficients are orders of magnitude larger than those expected from Newnham's scaling law. In ambient temperature nanoindentation measurements, (Y, Nb)‐stabilized δ‐Bi2O3 displays primary creep. These findings, which are strikingly similar to those reported for Gd‐doped ceria, support the suggestion that ion conducting ceramics with the fluorite structure, a large concentration of anion vacancies and anelastic behavior, may constitute a previously unknown class of electrostrictors.
