Phosphaalkene-substituted organo-group 15 compounds: synthesis and characterisation of (NHC) P-EtBu2 (E = P, As, Sb and Bi)

Phosphaalkene-substituted organo-group 15 compounds: synthesis and characterisation of (NHC) P-EtBu2 (E = P, As, Sb and Bi)
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DOI:
10.1039/c8cc00899j
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发表时间:
2018-03-14
影响因子:
4.9
通讯作者:
von Haenisch, Carsten
von Haenisch, Carsten
中科院分区:
化学2区
文献类型:
--
作者:
Balmer, Markus;Gottschling, Hannah;von Haenisch, Carsten

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在此,我们提出了新的15族元素化合物的合成和表征低价磷原子作为取代基。这一新的化合物系列包括较重的15族元素,代表了具有直接P-E键的罕见化合物组(E = P,As,Sb和Bi)。
Herein, we present the synthesis and characterisation of new group 15 element compounds with low valent phosphorus atoms as substituents. This new series of compounds includes the heavier group 15 elements and represents the rare group of compounds with a direct P-E bond (E = P, As, Sb and Bi).