Hydrodimerization of benzene to phenylcyclohexane over supported transition metal catalysts
Hydrodimerization of benzene to phenylcyclohexane over supported transition metal catalysts
复制标题
DOI：
10.1016/0021-9517(69)90447-3
复制
发表时间：
1969-04
影响因子：
7.3
通讯作者：
L. H. Slaugh;L. John
中科院分区：
文献类型：
--
作者：
L. H. Slaugh;L. John
苯在不同负载型过渡金属催化剂上加氢可高产率得到苯基环己烷。酸性和加氢活性是催化剂的必要性能。环己烯被认为是从金属氢化位点迁移到酸位点的关键中间体，在酸位点处随后发生苯的烷基化。
Phenylcyclohexane has been obtained in high yield from the hydrogenation of benzene over a variety of supported transition metal catalysts. Both acidity and hydrogenation activity are necessary catalyst properties. Cyclohexene is believed to be a key intermediate which migrates from metal hydrogenation sites to acid sites where subsequent alkylation of benzene occurs.