High Proton Conductivity in Prussian Blue Analogues and the Interference Effect by Magnetic Ordering
High Proton Conductivity in Prussian Blue Analogues and the Interference Effect by Magnetic Ordering
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DOI：
10.1021/ja100385f
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发表时间：
2010-05-19
影响因子：
15
通讯作者：
Tokoro, Hiroko
中科院分区：
文献类型：
--
作者：
Ohkoshi, Shin-ichi;Nakagawa, Kosuke;Tokoro, Hiroko
我们观察到Co[Cr(CN)(6)]（2/3）中心点zH(2)O和V[Cr(CN)(6)]（2/3）中心点zH(2)O上的质子电导率分别为1.2 × 10（-3）和1.6 × 10(-3) S cm(-1)，并且在磁相变温度以下，磁有序与离子电导率之间存在干扰效应。
We observed high proton conductivities of 1.2 x 10(-3) and 1.6 x 10(-3) S cm(-1) on Co[Cr(CN)(6)](2/3)center dot zH(2)O and V[Cr(CN)(6)](2/3)center dot zH(2)O, respectively, and an interference effect between magnetic ordering and ionic conduction below the magnetic phase transition temperature.