New di- and trinuclear complexes of ruthenium with octahedra joined on faces or edges. 4. Compounds containing [(R3P)3RuCl3RuCl3Ru(PR3)3]+ ions: structures, EPR spectroscopy, and electrochemistry
New di- and trinuclear complexes of ruthenium with octahedra joined on faces or edges. 4. Compounds containing [(R3P)3RuCl3RuCl3Ru(PR3)3]+ ions: structures, EPR spectroscopy, and electrochemistry
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新型钌二核和三核配合物与八面体连接在面或边缘上。
DOI：
10.1021/ic00023a019
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发表时间：
1991
影响因子：
4.6
通讯作者：
R. Torralba
中科院分区：
文献类型：
--
作者：
F. Cotton;R. Torralba
1980年报道了第一个由共面八面体线性排列组成的三核簇合物[Ru 3C 112] 4”，1983年详细讨论了它的电子结构。1989年，发现4存在相关的中性物种（PBu 3）2C 1 RuC 13 RuC 13 RuC 1（PBu 3）2，最近，我们描述了许多具有不同膦的其它此类分子。1此外，这些化合物的氧化产物[Ru 3C 18（PR 3）4]+已被分离为[SbF 6]-盐，并且已经获得了化学和电化学性质的证据。
The first trinuclear cluster consisting of a linear array of face-sharing octahedra,[Ru3C112] 4", was reported in 19802 and its electronic structure discussed in detail in 1983.3 In 1989, it was shown4 that the related neutral species (PBu3) 2C1RuC13RuC13RuC1 (PBu3) 2 exists, and quite recently we have described a number of other such molecules with different phosphines. 1 In addition, the oxidation products of these,[Ru3C18 (PR3) 4]+, have been isolated as the [SbF6]~ salts, and evidence of both the chemical and electrochemical nature has been