Development of Silicon-Mediated Ring-Forming Reactions for Carbocycles
Development of Silicon-Mediated Ring-Forming Reactions for Carbocycles
复制标题
硅介导的碳环成环反应的进展
DOI：
10.5059/yukigoseikyokaishi.55.774
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发表时间：
1997
影响因子：
0.2
通讯作者：
K. Takeda
中科院分区：
文献类型：
--
作者：
K. Takeda
由于在各种天然产物和理论上有趣的分子中发现了环系统，因此用于构建奇数碳环（例如五元环和七元环系统）的方法的开发已成为合成化学家非常感兴趣的主题。这篇综述描述了布鲁克重排介导的[3+2]和[3+4]环化方法，它们分别允许高效构建五元和七元碳环。
The development of methodologies for the construction of the odd-membered carbocycles such as five- and seven-membered ring systems has become a subject of great interest for synthetic chemists since the ring systems are found in a wide variety of natural products and theoretically interesting molecules. This review describes Brook rearrangement-mediated [3+2] and [3+4] annulation methodologies which permit highly efficient construction of five- and seven-membered carbocycles, respectively.