On a theory of the van der Waals adsorption of gases
On a theory of the van der Waals adsorption of gases
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DOI：
10.1021/ja01864a025
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发表时间：
1940-07-01
影响因子：
15
通讯作者：
Teller, E
中科院分区：
文献类型：
--
作者：
Brunauer, S;Deming, LS;Teller, E
1.在10~6-10~(-3)正常浓度范围内，测量了四丁基溴化铵在二苯醚中50℃的电导。2.场强高达20KV/cm时60、600和1000次循环的电导。在0.5-5.0×10~(-4)N的浓度范围内测得。3.对于低频，Wien效应符合Onsager理论，当朗之万弛豫时间与外加磁场的周期相当时，Wien效应出现色散。
1. The conductance of tetrabutylammonium bromide in diphenyl ether at 50 has been meas-ured at low voltage over the approximate con-centration range 10~ 6—10-3 normal. 2. Conductances at 60, 600 and 1000 cycles at field strengths up to 20 KV/cm. were measured in the concentration range 0.5-5.0 X 10-4 N. 3. For low frequencies, the Wien effect is in agreement with Onsager’s theory; when the Langevin time of relaxation becomes comparable to the period of the impressed field, a dispersion of the Wien effect appears.