Development and validation of a multiresidue method for the analysis of polybrominated diphenyl ethers, new brominated and organophosphorus flame retardants in sediment, sludge and dust
Development and validation of a multiresidue method for the analysis of polybrominated diphenyl ethers, new brominated and organophosphorus flame retardants in sediment, sludge and dust
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DOI：
10.1016/j.chroma.2013.07.028
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发表时间：
2013-08-30
影响因子：
4.1
通讯作者：
Lacorte, Silvia
中科院分区：
文献类型：
--
作者：
Cristale, Joyce;Lacorte, Silvia
本研究提出了一种多残留方法，用于同时提取，清理和分析沉积物，污水污泥和灰尘中的优先和新兴阻燃剂。研究的化合物包括八种多溴二苯醚同系物、九种新的溴化阻燃剂和十种有机磷阻燃剂。该分析方法基于乙酸乙酯/环己烷（5：2，v/v）超声辅助萃取，Florisil柱净化，气相色谱-串联质谱（GC-EI-MS/MS）分析。方法开发和验证方案包括加标样品、经认证的参比物质（用于粉尘）以及参与实验室间校准。该方法被证明是有效的和强大的提取和测定的三个家庭的阻燃剂家族在研究的固体基质。该方法适用于河流沉积物，污水污泥和灰尘样品，并允许检测27个研究阻燃剂中的24个。有机磷酸酯、BDE-209和十溴二苯基乙烷是检测到的最普遍的污染物。(c)2013爱思唯尔有限公司版权所有。
This study presents a multiresidue method for simultaneous extraction, clean-up and analysis of priority and emerging flame retardants in sediment, sewage sludge and dust. Studied compounds included eight polybrominated diphenyl ethers congeners, nine new brominated flame retardants and ten organophosphorus flame retardants. The analytical method was based on ultrasound-assisted extraction with ethyl acetate/cyclohexane (5:2, v/v), clean-up with Florisil cartridges and analysis by gas chromatography coupled to tandem mass spectrometry (GC-EI-MS/MS). Method development and validation protocol included spiked samples, certified reference material (for dust), and participation in an interlaboratory calibration. The method proved to be efficient and robust for extraction and determination of three families of flame retardants families in the studied solid matrices. The method was applied to river sediment, sewage sludge and dust samples, and allowed detection of 24 among the 27 studied flame retardants. Organophosphate esters, BDE-209 and decabromodiphenyl ethane were the most ubiquitous contaminants detected. (c) 2013 Elsevier B.V. All rights reserved.