Jacketed polymers: Controlled synthesis of mesogen-jacketed polymers and block copolymers
Jacketed polymers: Controlled synthesis of mesogen-jacketed polymers and block copolymers
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DOI：
10.1002/pola.23128
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发表时间：
2009-01
期刊：
影响因子：
--
通讯作者：
Longcheng Gao;Xinghe Fan;Zhihao Shen;Xiaofang Chen;Qifeng Zhou
中科院分区：
文献类型：
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作者：
Longcheng Gao;Xinghe Fan;Zhihao Shen;Xiaofang Chen;Qifeng Zhou
介晶夹套液晶聚合物的受控自由基聚合引发了人们对复杂结构以及具有受控分子量和窄分子量分布的明确线性均聚物合成的极大兴趣。本文重点介绍了线性均聚物、星形聚合物、超支化聚合物、接枝聚合物、嵌段共聚物、星形嵌段共聚物等的受控自由基聚合的合成策略。所采用的活性方法包括硝基氧介导的自由基聚合和原子转移自由基聚合。
The controlled radical polymerization of mesogen-jacketed liquid crystalline polymers has triggered great interests in synthesis of complex structures as well as well-defined linear homopolymers with controlled molecular weight and narrow molecular weight distributions. This review highlights the synthetic strategies of controlled radical polymerization of linear homopolymers, star polymers, superbranched polymers, graft polymers, block copolymers, star block copolymers, and so on. The employed living methods include nitroxide-mediated radical polymerization and atom transfer radical polymerization.