Flexible, planar integratable and all-solid-state micro-supercapacitors based on nanoporous gold/ manganese oxide hybrid electrodes via template plasma etching method
Flexible, planar integratable and all-solid-state micro-supercapacitors based on nanoporous gold/ manganese oxide hybrid electrodes via template plasma etching method
复制标题
基于纳米多孔金/氧化锰混合电极的模板等离子体蚀刻法柔性平面可集成全固态微型超级电容器
DOI：
10.1016/j.jallcom.2017.12.292
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发表时间：
2018
影响因子：
6.2
通讯作者：
Dai Ye
中科院分区：
文献类型：
--
作者：
Shi Xiaobo;Zeng Zhigang;Liao Chujian;Tao Shengying;Guo Erjuan;Long Xiao;Wang Xiaohong;Deng Dongmei;Dai Ye
Along with the rapid development of miniaturization of mobile devices and wearable integrated electronics system, flexible integrated micro electrical energy storage devices with high-performance, deformability and cycling stability will be the technological trend for a long time in the future. In this work, template plasma etching method and electrochemical deposition method have been combined to fabricate nanoporous gold/manganese oxide interdigitated electrodes that can be easily utilized in flexible micro-supercapacitors(MSCs). These MSCs exhibit relatively high specific capacitance of 18.47 mF cm−2in 0.5 M Na2SO4electrolyte and 11.58 mF cm−2in polyvinyl alcohol (PVA)/LiCl solid state electrolyte. A high energy density of 6.93 × 10−7Wh cm−2to 1.03 × 10−6Wh cm−2while power density ranging from 4.63 × 10−5W cm−2to 3.12 × 10−4W cm−2. The NPG/MnO2MSCs excellent long term cycling stability of 80.7% can be seen even after cycling for 5000 times. Moreover, the MSCs devices also demonstrate a sound flexibility and a superior frequency response (1.25 ms). In addition, the effects of various finger width and finger spacing on performance are compared, the critical importance of adjusting interdigitated structure is highlighted. This present research may provide an innovative avenue for the new prospective high-performance flexible micro-supercapacitors.
