Synthesis and characterization of the iron-sulfur cluster compounds [Fe4S5(MeCp)4](PF6)y (y = 0-2). X-ray structure determination of [Fe4S5(MeCp)4](PF6)
Synthesis and characterization of the iron-sulfur cluster compounds [Fe4S5(MeCp)4](PF6)y (y = 0-2). X-ray structure determination of [Fe4S5(MeCp)4](PF6)
复制标题
铁硫簇化合物[Fe4S5(MeCp)4](PF6)y (y = 0-2)的合成和表征。
DOI:
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发表时间:
1992
期刊:
影响因子:
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通讯作者:
J. Jordanov
中科院分区:
文献类型:
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作者:
H. Blonk;J. Mesman;J. Linden;J. J. Steggerda;J. Smits;G. Beurskens;P. Beurskens;C. Tonon;J. Jordanov
The series of iron-sulfur cluster compounds [Fe 4 S 5 (MeCp) 4 ](PF 6 ) y (y=0-2) is readily prepared by reaction of [Fe(MeCp)(CO) 2 ] 2 with an excess of sulfur in refluxing toluene followed by a number of suitable synthesis and purification steps. The structure [Fe 4 S 5 (MeCp) 4 ](PF 6 ) was determined crystallographically