Matrix line in pulsed electron-nuclear double resonance spectra
Matrix line in pulsed electron-nuclear double resonance spectra
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DOI：
10.1006/jmre.1998.1568
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发表时间：
1998-12-01
影响因子：
2.2
通讯作者：
Kawamori, A
中科院分区：
文献类型：
--
作者：
Astashkin, AV;Kawamori, A
Mims和Davies电子-核双共振（ENDOR）谱中的强线是由于未成对电子与远距离基质核的超精细相互作用引起的，它起源于射频脉冲同时反转大量的核自旋。理论表达式描述矩阵ENDOR效应推导和实验验证。(C)北京：科学出版社.
The intense line in Mims and Davies electron-nuclear double resonance (ENDOR) spectra due to the hyperfine interactions of an unpaired electron with distant matrix nuclei is shown to originate from a simultaneous inversion of a large number of nuclear spins by a radiofrequency pulse. Theoretical expressions describing the matrix ENDOR effect are derived and verified experimentally. (C) 1998 Academic Press.