Rhodium-catalyzed Heck-type reaction of arylboronic acids with α,β-unsaturated esters: tuning β-hydrogen elimination vs. hydrolysis of alkylrhodium species
Rhodium-catalyzed Heck-type reaction of arylboronic acids with α,β-unsaturated esters: tuning β-hydrogen elimination vs. hydrolysis of alkylrhodium species
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芳基硼酸与 α,β-不饱和酯的铑催化 Heck 型反应：调整 β-氢消除与烷基铑物质的水解
DOI：
10.1039/b305771m
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发表时间：
2003
影响因子：
4.9
通讯作者：
Jie Tang
中科院分区：
文献类型：
--
作者：
Gang Zou;Zhiyong Wang;Junru Zhu;Jie Tang
以氯化铑为催化剂，芳基硼酸与α，β-不饱和酯发生了Heck型偶联反应，表明铑的空间位阻可以调控Rh-C键的水解.
The elusive rhodium-catalyzed Heck-type coupling of arylboronic acids with α,β-unsaturated esters is effected using rhodium chloride as catalyst, indicating the hydrolysis of Rh–C bond could be finely tuned by the steric environment around rhodium.