Synthesis of Glycosylated Metal Phthalocyanines and Naphthalocyanines

Synthesis of Glycosylated Metal Phthalocyanines and Naphthalocyanines
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糖基化金属酞菁和萘酞菁的合成

DOI：
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发表时间：
2012
期刊：
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通讯作者：
M. Hanack
M. Hanack
中科院分区：
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文献类型：
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作者：
A. Lyubimtsev;Z. Iqbal;Goeran Crucius;S. Syrbu;T. Ziegler;M. Hanack

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本文第一部分综述了单取代、二取代和四取代糖基化邻苯二甲腈的合成方法，它们是制备相应糖基化金属酞菁的主要原料。在第二部分中，综述了对称和不对称四糖基和八糖基锌的制备方法，其中的糖基是以异构性或通过另一个羟基连接到酞菁大环上的，以及其他结构不同的糖基化金属酞菁。
The first part of this review summarizes methods for the syntheses of mono-, di-, and tetra-substituted glycosylated phthalonitriles, which are the main starting materials for the preparation of the corresponding glycosylated metal phthalocyanines. In the second part the preparation of symmetrically and unsymmetrically tetra- and octa- glycosylated zinc phthalocyanines in which the sugar is attached either anomerically or via another one of its OH-groups to the phthalocyanine macrocycle as well as other structurally different glycosylated metal phthalocyanines are reviewed.