Chemical instability of Cu3(BTC)2 by reaction with thiols
Chemical instability of Cu3(BTC)2 by reaction with thiols
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DOI：
10.1016/j.catcom.2011.03.018
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发表时间：
2011-06-10
影响因子：
3.7
通讯作者：
Garcia, Hermenegildo
中科院分区：
文献类型：
--
作者：
Dhakshinamoorthy, Amarajothi;Alvaro, Mercedes;Garcia, Hermenegildo
与Fe(BTC)(BTC：1，3，5-苯三甲酸酯)不同，被广泛用作固体催化剂的商用金属有机骨架Cu3(BTC)(2)在温和的反应条件下与硫醇接触时晶体结构崩塌，形成铜纳米颗粒。(C)2011爱思唯尔B.V.保留所有权利。
In contrast to Fe(BTC) (BTC: 1,3,5-benzenetricarboxylate), the crystal structure of Cu-3(BTC)(2), a commercial metal organic framework widely used as solid catalyst, collapses when contacted with thiols under mild reaction conditions forming copper nanoparticles. (C) 2011 Elsevier B.V. All rights reserved.