Quadrupole Coupling in Benzonitrile. An Application of Microwave Fourier Transform Spectroscopy
Quadrupole Coupling in Benzonitrile. An Application of Microwave Fourier Transform Spectroscopy
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苯甲腈中的四极杆耦合。
DOI：
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发表时间：
1981
期刊：
影响因子：
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通讯作者：
H. Dreizler
中科院分区：
文献类型：
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作者：
E. Fliege;G. Bestmann;R. Schwarz;H. Dreizler
Fig. 1.用MWFT光谱法测量的K-dublett 642 - 541、643 - 542的氮-hfs。以50 ns的步长记录1024个点的瞬态发射。测量时间10分钟，10 MHz范围。在傅立叶变换之前添加了多达2048个点的零。10 kHz距离处的频谱点。频率由假定的三点插值洛伦兹分布计算。压力0.1 mT，温度-57 °C。
Fig. 1. Nitrogen-hfs of the K-dublett 642 — 541, 643 — 542 measured with MWFT spectroscopy. Transient emission recorded in steps of 50 ns for 1024 points. Measuring time 10 min. for a 10 MHz range. Zeros up to 2048 points were added prior to the Fourier transformation. Spectral points at 10 kHz distance. Frequencies calculated by three point interpolation Lorentz profile assumed. Pressure 0.1 mT, temperature — 57 °C.