Molecular engineering of fluoroether electrolytes for lithium metal batteries

Molecular engineering of fluoroether electrolytes for lithium metal batteries
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DOI:
10.1039/d2me00135g
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发表时间:
2022
期刊:
Molecular Systems Design & Engineering
影响因子:
--
通讯作者:
Yuxi Chen;Elizabeth M. Y. Lee;Phwey S Gil;P. Ma;Chibueze V. Amanchukwu;J. D. de Pablo
Yuxi Chen;Elizabeth M. Y. Lee;Phwey S Gil;P. Ma;Chibueze V. Amanchukwu;J. D. de Pablo
中科院分区:
其他
文献类型:
--
作者:
Yuxi Chen;Elizabeth M. Y. Lee;Phwey S Gil;P. Ma;Chibueze V. Amanchukwu;J. D. de Pablo

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短链溶剂中的高溶剂自扩散率和长链溶剂中的低溶剂化自由能之间的临界平衡导致用于实现氟醚溶剂的高离子电导率的最佳溶剂尺寸。
A critical balance between high solvent self-diffusivity in short-chain solvents and low solvation free energy in long-chain solvents leads to an optimal solvent size for achieving high ionic conductivity for fluoroether solvents.