Dendritic closomers: novel spherical hybrid dendrimers.

Dendritic closomers: novel spherical hybrid dendrimers.
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树枝状闭合聚合物:新型球形杂化树枝状聚合物。

DOI:
10.1039/c3cc40597d
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发表时间:
2013
期刊:
Chemical communications (Cambridge, England)
影响因子:
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通讯作者:
Hawthorne,MFrederick
Hawthorne,MFrederick
中科院分区:
--
文献类型:
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作者:
Pushechnikov,Alexei;Jalisatgi,SatishS;Hawthorne,MFrederick

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我们报告的单分散PAMAM型树枝状聚合物的基础上的dodecahydroxy closo-dodecaborane支架建设。二十面体核的理想球形度和高官能团密度允许容易获得具有刚性、均匀形状的外表面的混合树枝状聚合物(树枝状封闭体)。
We report construction of monodisperse PAMAM-type dendrimers based on a dodecahydroxy closo-dodecaborane scaffold. The ideal sphericity and high functional group density of the icosahedral core permits ready access to hybrid dendrimers (dendritic closomers) having rigid, uniformly shaped exterior surfaces.