Cooperative spin transition in a lipid layer like system

Cooperative spin transition in a lipid layer like system
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DOI:
10.1039/c1cc12162f
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发表时间:
2011-01-01
影响因子:
4.9
通讯作者:
Garcia, Yann
Garcia, Yann
中科院分区:
化学2区
文献类型:
--
作者:
Schlamp, Stephan;Weber, Birgit;Garcia, Yann

文献摘要

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一种新型铁(II)单核自旋跃迁配合物[FeL(py)(2)]在225 K左右表现出突然的自旋跃迁,并伴有非常宽的热滞回线(类似于50 K),其范围超过100 K。低自旋和高自旋状态下的晶体结构分析揭示了该配合物分子的脂质层状排列,并提供了对自旋转换机制的见解。
A novel iron(II) mononuclear spin transition complex [FeL(py)(2)] displays an abrupt spin transition around 225 K accompanied by a very wide thermal hysteresis loop (similar to 50 K) that spreads out over 100 K. Crystal structure analysis in both low-spin and high-spin states reveals a lipid layer-like arrangement of the complex molecules and provides insights into the spin switching mechanism.