Cooperative spin transition in a lipid layer like system
Cooperative spin transition in a lipid layer like system
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DOI:
10.1039/c1cc12162f
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发表时间:
2011-01-01
影响因子:
4.9
通讯作者:
Garcia, Yann
中科院分区:
文献类型:
--
作者:
Schlamp, Stephan;Weber, Birgit;Garcia, Yann
A novel iron(II) mononuclear spin transition complex [FeL(py)(2)] displays an abrupt spin transition around 225 K accompanied by a very wide thermal hysteresis loop (similar to 50 K) that spreads out over 100 K. Crystal structure analysis in both low-spin and high-spin states reveals a lipid layer-like arrangement of the complex molecules and provides insights into the spin switching mechanism.