Extraordinary magnetocaloric effect of Fe-based bulk glassy rods by combining fluxing treatment and J-quenching technique

Extraordinary magnetocaloric effect of Fe-based bulk glassy rods by combining fluxing treatment and J-quenching technique
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熔剂处理与 J 淬火技术相结合的铁基大块玻璃棒的非凡磁热效应

DOI:
10.1016/j.jallcom.2016.05.142
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发表时间:
2016
影响因子:
6.2
通讯作者:
Inoue Akihisa
Inoue Akihisa
中科院分区:
材料科学2区
文献类型:
--
作者:
Yang Weiming;Huo Juntao;Liu Haishun;Li Jiawei;Song Lijian;Li Qiang;Xue Lin;Shen Baolong;Inoue Akihisa

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本文研究了Fe_(80)P_(13)C_7大块玻璃棒的反常磁热效应。在1.5 T下的磁熵变(ΔSM)和制冷量(RC)分别可达2.20 J kg− 1 K − 1和125 J kg−1,是目前三元铁基玻璃合金中最大的值。结果表明,随着磁场的增加,磁热效应-温度曲线逐渐变为双峰,Δ SM峰变宽,RC变大。Fe_(80)P_(13)C_(7)的磁热效应可能是由于磁性转变和自旋重取向转变共存的结果。
The extraordinary magnetocaloric effect of Fe80P13C7bulk glassy rods has been studied. The magnetic entropy change (ΔSM) and refrigerant capacity (RC) values under 1.5 T can reach 2.20 J kg−1K−1and 125 J kg−1, respectively, which are the largest values among present ternary Fe-based glassy alloys. It is found that the magnetocaloric effectvstemperature curve gradually changes into two peaks with increasing magnetic fields, leading to a much wider ΔSMpeak and thus a largerRC. This extraordinary magnetocaloric effect in Fe80P13C7may be attributed to the coexistence of magnetic transition and spin reorientation transition.