Hydration and dynamic behavior of poly(N-isopropylacrylamide)s in aqueous solution:: A sharp phase transition at the lower critical solution temperature
Hydration and dynamic behavior of poly(N-isopropylacrylamide)s in aqueous solution:: A sharp phase transition at the lower critical solution temperature
复制标题
DOI：
10.1021/ja063990i
复制
发表时间：
2006-08-09
影响因子：
15
通讯作者：
Shikata, Toshiyuki
中科院分区：
文献类型：
--
作者：
Ono, Yousuke;Shikata, Toshiyuki
采用高频介电弛豫技术，在均相水溶液中每个聚（N-异丙基丙烯酰胺）单体单元的水合水分子的数目被确定为11，精确地并且重新低于32 °C的较低临界溶解温度。
The number of hydrated water molecules per poly(N-isopropylacrylamide) monomer unit in homogeneous aqueous solution was determined to be 11 exactly and anew below the lower critical solution temperature of 32 °C employing high-frequency dielectric relaxation techniques.