Transition of oscillatory mechanism for methanol electro-oxidation on nano-structured nickel hydroxide film (NNHF) electrode.
Transition of oscillatory mechanism for methanol electro-oxidation on nano-structured nickel hydroxide film (NNHF) electrode.
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DOI：
10.1039/b401743a
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发表时间：
2004-06
影响因子：
4.9
通讯作者：
Wei Huang;Zelin Li;Youdi Peng;Zhen-jiang Niu
中科院分区：
文献类型：
--
作者：
Wei Huang;Zelin Li;Youdi Peng;Zhen-jiang Niu
与铂电极上CO(Ad)的生成和去除不同，NNHF电极上甲醇电氧化的振荡现象是由电荷转移、扩散和对流传质耦合引起的。
Instead of CO(ad) formation and removal as on Pt electrodes, coupling of charge transfer with diffusion and convection mass transfer accounts for the oscillation found in the methanol electro-oxidation on the NNHF electrode.