Al0.5TiZrPdCuNi High-Entropy (H-E) Alloy Developed through Ti20Zr20Pd20Cu20Ni20 H-E Glassy Alloy Comprising Inter-Transition Metals

Al0.5TiZrPdCuNi High-Entropy (H-E) Alloy Developed through Ti20Zr20Pd20Cu20Ni20 H-E Glassy Alloy Comprising Inter-Transition Metals
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Al0.5TiZrPdCuNi 高熵 (H-E) 合金是通过包含过渡金属的 Ti20Zr20Pd20Cu20Ni20 H-E 玻璃态合金开发的

DOI:
10.2320/matertrans.m2012370
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发表时间:
2013-05
影响因子:
1.2
通讯作者:
Shengli Zhu
Shengli Zhu
中科院分区:
材料科学4区
文献类型:
--
作者:
Wei Zhang;Yoshihiko Yokoyama;Kunio Yubuta;Shengli Zhu

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An Al0.5TiZrPdCuNi high-entropy (H-E) alloy with a bcc single phase was found through a Ti20Zr20Pd20Cu20Ni20 H-E glassy alloy designed based on equi-atomicity inherent to H-E alloys. The constituent elements and the composition of the Ti20Zr20Pd20Cu20Ni20 alloy were determined by regarding a binary Cu64Zr36 bulk metallic glass as Cu60Zr40 alloy and subsequent replacements of the Cu and Zr atoms with other late- and early-transition metals, respectively. The Ti20Zr20Pd20Cu20Ni20 alloy in a ribbon shape forms into a glassy single phase. The addition of 0.5Al to the Ti20Zr20Pd20Cu20Ni20 H-E glassy alloy resulted in forming a bcc single phase for a rod specimen with a diameter of 1.5mm. The analysis revealed that the Al0.5TiZrPdCuNi H-E alloy is characterized by mixing enthalpy of ¹46.7kJ·mol ¹1 and Delta parameter of 8.8, which are considerably larger and negative for the former and larger for the latter against the conventional H-E alloys. [doi:10.2320/matertrans.M2012370]
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