Reversible arm-off dissociation of the tripodal MeC(CH2PPh2)3 in HRh(CO)[MeC(CH2PPh2)3] under hydroformylation conditions

Reversible arm-off dissociation of the tripodal MeC(CH2PPh2)3 in HRh(CO)[MeC(CH2PPh2)3] under hydroformylation conditions
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加氢甲酰化条件下 HRh(CO)[MeC(CH2PPh2)3] 中三足 MeC(CH2PPh2)3 的可逆臂离解

DOI:
10.1021/om00057a004
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发表时间:
1991
期刊:
影响因子:
2.8
通讯作者:
I. Horváth
I. Horváth
中科院分区:
化学2区
文献类型:
--
作者:
G. Kiss;I. Horváth

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三足配体MeC (CH2PPh2) 3在HRh (CO)中的可逆旋臂解离[»?]采用高压红外光谱和核磁共振光谱研究了H2/CO(1:1)作用下3- mec -(CH2PPh2) 3](1)。的形成
The reversible arm-off dissociation of the tripodal ligand MeC (CH2PPh2) 3 in HRh (CO)[»? 3-MeC-(CH2PPh2) 3](1) under H2/CO (1: 1) was studied by high-pressure IR and NMR spectroscopy. The formation of