Materials for organic electroluminescence: aluminium vs. boron
Materials for organic electroluminescence: aluminium vs. boron
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DOI：
10.1016/s0379-6779(99)00400-2
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发表时间：
2000-06-01
期刊：
影响因子：
4.4
通讯作者：
Hudson, AJ
中科院分区：
文献类型：
--
作者：
Anderson, S;Weaver, MS;Hudson, AJ
我们报道了硼配合物1-7的合成及其在溶液和固体中的吸收和发射（光致发光和电致发光）特性。我们比较它们的电子性质的Alq（3）类似物，并使用分子轨道（MO）计算合理化的λ（最大）的位移所造成的系统取代甲基周围的8-羟基喹啉配体部分的外围。(C)2000 Elsevier Science S.A. All rights reserved.
We report the synthesis of boron complexes 1-7 and their absorption and emission (photoluminescence and electroluminescence) characteristics in solution and in the solid state. We compare their electronic properties to those of the Alq(3) analogues, and use molecular orbiral (MO) calculations to rationalise the lambda(max) shifts caused by systematically substituting methyl groups around the periphery of the 8-hydroxyquinoline ligand moiety. (C) 2000 Elsevier Science S.A. All rights reserved.