Copper-mediated trifluoromethylation of arylboronic acids by trifluoromethyl sulfonium salts
Copper-mediated trifluoromethylation of arylboronic acids by trifluoromethyl sulfonium salts
复制标题
三氟甲基锍盐铜介导的芳基硼酸三氟甲基化
DOI：
10.1039/c1cc13460d
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发表时间：
2011-01-01
影响因子：
4.9
通讯作者：
Xiao, Ji-Chang
中科院分区：
文献类型：
--
作者：
Zhang, Cheng-Pan;Cai, Ji;Xiao, Ji-Chang
研究了芳基硼酸在[Ph2SCF3](+)[OTf](-)/Cu(0)体系中的无配体三氟甲基化反应。具有不同官能团的芳基、烯基和杂芳基硼酸是该反应的适宜底物。结果表明，在该反应条件下，生成了CuCF3物种。
The ligand-free trifluoromethylation of arylboronic acids with a [Ph2SCF3](+)[OTf](-)/Cu(0) system has been carefully investigated. Aryl-, alkenyl- and heteroarylboronic acids with a variety of functional groups were suitable substrates for this reaction. It is suggested that a CuCF3 species is formed under the reaction conditions.