Ionothermal synthesis of two oxalate-bridged lanthanide(III) chains with slow magnetization relaxation by using a deep eutectic solvent.
Ionothermal synthesis of two oxalate-bridged lanthanide(III) chains with slow magnetization relaxation by using a deep eutectic solvent.
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DOI：
10.1039/c3dt51816g
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发表时间：
2013-08
影响因子：
4
通讯作者：
Y. Meng;Jun‐Liang Liu;Ze-Min Zhang;Wei-Quan Lin;Zhuo-jia Lin;M. Tong
中科院分区：
文献类型：
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作者：
Y. Meng;Jun‐Liang Liu;Ze-Min Zhang;Wei-Quan Lin;Zhuo-jia Lin;M. Tong
以氯化胆碱-草酸共晶混合物为溶剂和结构导向剂，首次离子热法制备了两种新型的同结构草酸桥接镧系（III）链（胆碱）[Ln(ox)(H2O)3Cl]Cl·H2O (Ln = Dy/Er)，两者均表现出场致慢弛豫现象。
Two novel isostructural oxalate-bridged lanthanide(III) chains, (choline)[Ln(ox)(H2O)3Cl]Cl·H2O (Ln = Dy/Er), were first obtained ionothermally by using a choline chloride-oxalic acid eutectic mixture as both solvent and structure-directing agent, both of which show field-induced slow relaxation of magnetization.