Preparation of polythiophene microrods with ordered chain alignment using nanoporous coordination template
Preparation of polythiophene microrods with ordered chain alignment using nanoporous coordination template
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DOI：
10.1039/c7py00309a
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发表时间：
2017-09-14
影响因子：
4.6
通讯作者：
Uemura, Takashi
中科院分区：
文献类型：
--
作者：
Kitao, Takashi;MacLean, Michael W. A.;Uemura, Takashi
聚合物材料的性能可以通过大分子排列来放大。以多孔配位聚合物（PCP）为模板，实现了非取代聚噻吩分子链的高度有序排列。由于扩展的共轭体系，所获得的各向异性聚合物颗粒表现出比通过溶液聚合制备的聚噻吩更高的电导率。
The properties of polymeric materials can be amplified by macromolecular alignment. The highly ordered chain alignment of unsubstituted polythiophene, an unprocessable polymer, has been achieved using a porous coordination polymer (PCP) as a template. Due to the extended conjugation system, the obtained anisotropic polymer particles exhibit higher conductivity than that of polythiophene prepared by solution polymerization.