Developments in the Coordination Chemistry of Europium(II).

Developments in the Coordination Chemistry of Europium(II).
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DOI:
10.1002/ejic.201200159
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发表时间:
2012-10-01
影响因子:
2.3
通讯作者:
Allen, Matthew J.
Allen, Matthew J.
中科院分区:
化学3区
文献类型:
--
作者:
Garcia, Joel;Allen, Matthew J.

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综述了近年来Eu ~(2+)配位化学的研究进展。总结了自2000年以来报道的用于生成离散的含Eu 2+的络合物的常见合成路线,随后描述了这些络合物的反应性及其在还原化学、聚合、发光和作为磁共振成像的造影剂中的应用。随着Eu ~(2+)配位化学的迅速发展,含Eu ~(2+)配合物在合成化学、材料科学和医学等领域的应用日益广泛。
Recent advances in the coordination chemistry of Eu2+ are reviewed. Common synthetic routes for generating discrete Eu2+-containing complexes reported since 2000 are summarized, followed by a description of the reactivity of these complexes and their applications in reduction chemistry, polymerization, luminescence, and as contrast agents for magnetic resonance imaging. Rapid development of the coordination chemistry of Eu2+ has led to an upsurge in the utilization of Eu2+-containing complexes in synthetic chemistry, materials science, and medicine.
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