Synthesis and Properties of Alkylperoxocobalt(III) Porphyrin and Porphycene
Synthesis and Properties of Alkylperoxocobalt(III) Porphyrin and Porphycene
复制标题
烷基过氧钴(III)卟啉和卟啉的合成及性能
DOI：
10.1246/cl.2000.90
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发表时间：
2000
影响因子：
1.6
通讯作者：
Y. Hisaeda
中科院分区：
文献类型：
--
作者：
Takashi Hayashi;Kenshi Okazaki;H. Shimakoshi;F. Tani;Y. Naruta;Y. Hisaeda
已经制备了卟啉和紫菜嗪的烷基钴（III）和烷基过氧钴（III）物种，并通过紫外 - 可见光谱和1H核磁共振光谱测量对其进行了表征。烷基过氧钴物种的热分解通过Co - O键或O - O键的断裂进行，这取决于轴向配体的配位情况。
Alkylcobalt(III) and alkylperoxocobalt(III) species of porphyrin and porphycene have been prepared and characterized by UV-vis and 1H NMR spectroscopic measurements. Thermal decomposition of the alkylperoxocobalt species proceeds via Co–O or O–O bond cleavage, which depends on the coordination of an axial ligand.