Activation of Molecular Hydrogen by Arylcarbenes
Activation of Molecular Hydrogen by Arylcarbenes
复制标题
DOI：
10.1002/chem.201804657
复制
发表时间：
2018-12-12
影响因子：
4.3
通讯作者：
Sander, Wolfram
中科院分区：
文献类型：
--
作者：
Mendez-Vega, Enrique;Maehara, Mika;Sander, Wolfram
研究了低温下二苯基卡宾1、荧叉2和二苯并环庚二烯3在固体H-2和D-2基质中以及在H-2和D-2掺杂的Ar基质中的加氢反应。卡宾对H-2的反应性按1级增加
The hydrogenation reactions of diphenylcarbene 1, fluorenylidene 2, and dibenzocycloheptadienylidene 3 were investigated in solid H-2 and D-2 matrices and in H-2- and D-2-doped argon matrices at cryogenic temperatures. The reactivity of the carbenes towards H-2 increases in the order 1