Unexpected formation of 2-amino-(1-(2-nitrophenylsulfinyl)azulene by the reaction of 2-aminoazulene with 2-nitrobenzenesulfonyl chloride
Unexpected formation of 2-amino-(1-(2-nitrophenylsulfinyl)azulene by the reaction of 2-aminoazulene with 2-nitrobenzenesulfonyl chloride
复制标题
2-氨基甘菊环与 2-硝基苯磺酰氯反应意外生成 2-氨基-(1-(2-硝基苯基亚磺酰基)甘菊环
DOI：
10.1002/hc.21173
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发表时间：
2014
期刊：
影响因子：
--
通讯作者：
T. Gunji
中科院分区：
文献类型：
--
作者：
H. Nakagawa;S. Tsukada;N. Abe;T. Gunji
以2‐氨基-(1‐（2‐硝基苯磺酰氯）为原料，合成了2‐氨基-(1‐（2‐硝基苯磺酰）唑烯衍生物。通过X射线衍射分析确定了这些化合物的晶体结构。硫原子衍生的鼻基具有独特的几何形状。此外，还证明了使用4‐硝基苯磺酰氯的反应。
2‐Amino‐(1‐(2‐nitrophenylsulfinyl)azulene derivatives were synthesized by the reaction of 2‐aminoazulene with 2‐nitrobenzenesulfonyl chloride. Crystal structures of these compounds were determined by X‐ray diffraction analysis. The sulfur atom derived nosyl group shows unique geometry. Furthermore, a reaction using 4‐nitrobenzenesulfonyl chloride is also demonstrated.