PHOTOELECTRON SPECTROSCOPY OF TRANSIENT SPECIES - CS MOLECULE
PHOTOELECTRON SPECTROSCOPY OF TRANSIENT SPECIES - CS MOLECULE
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DOI：
10.1039/dc9725400048
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发表时间：
1972-01-01
影响因子：
3.4
通讯作者：
SMITH, DJ
中科院分区：
文献类型：
--
作者：
JONATHAN, N;MORRIS, A;SMITH, DJ
报道了二硫化碳或二硫化碳/稀有气体混合物无极放电形成的CS分子的真空紫外光电子能谱。观察到与前四个电离势相对应的四个带，在每种情况下都具有相关的振动精细结构。通过与CNDO计算CS+的结果以及N2和CO的计算和观测值进行比较，确定了这些波段的电离跃迁。
The vacuum ultra-violet photoelectron spectrum of the CS molecule formed by electrodeless discharge of carbon disulphide or carbon disulphide/rare gas mixtures is reported. Four bands corresponding to the first four ionization potentials are observed, with associated vibrational fine structure in each case. The ionizing transitions responsible for these bands are assigned by comparison with the results of a CNDO calculation of CS+ and with the calculated and observed values for N2 and CO.