Palladium-catalyzed carboboration of alkynes using chloroborane and organozirconium reagents
Palladium-catalyzed carboboration of alkynes using chloroborane and organozirconium reagents
复制标题
DOI：
10.1039/b809433k
复制
发表时间：
2008-01-01
影响因子：
4.9
通讯作者：
Suginome, Michinori
中科院分区：
文献类型：
--
作者：
Daini, Masaki;Suginome, Michinori
在钯催化剂存在下，双（二烷基氨基）氯硼烷、炔和有机锆试剂发生三组分偶联反应，通过碳-碳三键的顺式碳硼化反应生成立体定向的烯基硼烷衍生物。
Three-component coupling of bis(dialkylamino)chloroborane, alkynes and organozirconium reagents proceeded in the presence of palladium catalysts, leading to the formation of stereo-defined alkenylborane derivatives via cis-carboboration of carbon-carbon triple bonds.