Photochemical synthesis of the cyanodiacetylene HC(5)N: a cryogenic matrix experiment.
Photochemical synthesis of the cyanodiacetylene HC(5)N: a cryogenic matrix experiment.
复制标题
氰基二乙炔 HC(5)N 的光化学合成：低温基质实验。
DOI：
10.1021/jp055582r
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发表时间：
2006
影响因子：
2.9
通讯作者：
N. Pietri
中科院分区：
文献类型：
--
作者：
A. Coupeaud;R. Kołos;I. Couturier;J. Aycard;N. Pietri
本文研究了分子间络合物氰乙炔：乙炔和二氰乙炔：乙炔在10 K固体氩基质中的反应性。FTIR测量，连同（2）H，（15）N，（13）C标记实验和密度泛函理论（DFT）计算（B3 LYP/aug-cc-pVTZ），指出氰基二乙炔HC（5）N（氰基丁二炔）的形成。这种合成路线对于泰坦大气的化学模型具有潜在的重要性。
The reactivity of intermolecular complexes cyanoacetylene:acetylene and dicyanoacetylene:acetylene, trapped in solid argon matrixes at 10 K and irradiated with vacuum UV, has been studied. FTIR measurements, together with (2)H, (15)N, (13)C labeling experiments and with density functional theory (DFT) calculations (B3LYP/aug-cc-pVTZ), pointed to the formation of cyanodiacetylene HC(5)N (cyanobutadiyne). This synthetic route is potentially important for chemical models of the Titan's atmosphere.