Ligands derived from tetrathiafulvalene: building blocks for multifunctional materials.
Ligands derived from tetrathiafulvalene: building blocks for multifunctional materials.
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DOI：
10.1039/c0dt00610f
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发表时间：
2010-11
影响因子：
4
通讯作者：
M. Shatruk;L. Ray
中科院分区：
文献类型：
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作者：
M. Shatruk;L. Ray
在过去的十年中，四硫富瓦烯（TTF）的配位化学取得了许多进展。已经合成了各种配体，其中金属结合官能团连接到TTF单元，并用于制备金属络合物。该观点总结了含TTF配体及其金属配合物的主要类型，并概述了在多功能分子材料的设计和组装中使用这些构建块的潜力。
The last decade has witnessed many advances in the coordination chemistry of tetrathiafulvalene (TTF). Various ligands, in which a metal-binding functionality is attached to the TTF unit, have been synthesized and used for the preparation of metal complexes. This Perspective summarizes the main types of TTF-containing ligands and their metal complexes and outlines the potential for the use of these building blocks in the design and assembly of multifunctional molecular materials.