Crystal structure of mono[3-(2-imidazolylthio)]-altro-beta-cyclodextrin: elliptical distortion of the cavity and unique 'Yin-Yang' stacking.
Crystal structure of mono[3-(2-imidazolylthio)]-altro-beta-cyclodextrin: elliptical distortion of the cavity and unique 'Yin-Yang' stacking.
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DOI：
10.1039/b303788f
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发表时间：
2003-06
影响因子：
4.9
通讯作者：
H. Lindner;De-Qi Yuan;K. Fujita;Koushi Kubo;F. Lichtenthaler
中科院分区：
文献类型：
--
作者：
H. Lindner;De-Qi Yuan;K. Fujita;Koushi Kubo;F. Lichtenthaler
标题化合物由于阿卓糖部分的不寻常的1C4几何形状而椭圆变形。在包装中，一个独特的四重螺旋结构是精心制作的头对头二聚体作为重复的主题。咪唑基部分相互驻留在彼此的空腔上，从而类似于阴阳类型的拮抗平衡。
The title compound is elliptically distorted due to the unusual 1C4 geometry of the altrose portion. In packing, a unique fourfold helical structure is elaborated with head-to-head dimers as the repeating motif. The imidazolyl moieties mutually reside on each other's cavities thereby resembling the Yin-Yang type balancing of antagonisms.