A convenient synthesis of crystalline potassium phosphate‐18O4 (monobasic) of high isotopic purity

A convenient synthesis of crystalline potassium phosphate‐18O4 (monobasic) of high isotopic purity
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一种高同位素纯度结晶磷酸钾-18O4(一元)的便捷合成

DOI:
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发表时间:
1978
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影响因子:
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通讯作者:
R. L. Etten
R. L. Etten
中科院分区:
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文献类型:
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作者:
J. Risley;R. L. Etten

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本文叙述了以PCl_5和99%水~(18)O为原料合成高(~ 90%)同位素纯度的结晶磷酸钾~(18)O_4(单硼酸盐)的方法。不受偏磷酸盐和焦磷酸盐污染的盐的产率为85%。
The synthesis of crystalline potassium phosphate-18O4 (monobasic) of high (∼ 90%) isotopic purity starting with PCl5 and 99% water-18O is described. The yield of the salt free from contamination by metaphosphates and pyrophosphate is 85%.