cis-[N-(4-Chlorobenzyl)iminodiacetato-κ3N,O,O′]bis(1H-imidazole-κN3)-copper(II)

cis-[N-(4-Chlorobenzyl)iminodiacetato-κ3N,O,O′]bis(1H-imidazole-κN3)-copper(II)
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DOI:
10.1107/s160053680702288x
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发表时间:
2007-06-01
影响因子:
0.9
通讯作者:
Choquesillo-Lazarte, Duane
Choquesillo-Lazarte, Duane
中科院分区:
其他
文献类型:
--
作者:
Brandi-Blanco, Maria Pilar;de Benavides-Gimenez, Maria Magdalena;Choquesillo-Lazarte, Duane

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在标题化合物[Cu(C11H10ClNO4)(C3H4N)(2)]中,铜(II)原子处于四方锥体配位构型,两个咪唑配体处于顺位,N-(4-氯苯基)亚氨基二乙酸酯配体占据顶位和两个顺位。在晶体结构中,分子通过N-H中心点O氢键连接成片状。
In the title compound, [ Cu( C11H10ClNO4)( C3H4N) (2)], the Cu (II) atom is in a square- pyramidal coordination geometry, with the two imidazole ligands in cis positions and the N-( 4- chlorobenzyl) iminodiacetate ligand occupying the apical and two cisbasal positions. In the crystal structure, molecules are linked into sheets by N - H center dot center dot center dot O hydrogen bonds.