Spin-crossover cobalt(II) compound with banana-shaped structure
Spin-crossover cobalt(II) compound with banana-shaped structure
复制标题
DOI：
10.1021/ic051059f
复制
发表时间：
2005-10-17
影响因子：
4.6
通讯作者：
Maeda, Y
中科院分区：
文献类型：
--
作者：
Hayami, S;Moriyama, R;Maeda, Y
以三联吡啶为骨架，合成了具有长烷基链的香蕉形自旋交叉（SCO）钴（II）配合物[Co(C16-terpy)(2)](BPh4)(2)(1)。化合物1表现出非常缓慢的SCO行为和介电常数的变化。这表明SCO材料可以用于电子器件。
A banana-shaped spin-crossover (SCO) cobalt(II) complex [Co(C16-terpy)(2)](BPh4)(2) (1) with long alkyl chains, based on a terpyricline frame, was synthesized. Compound 1 exhibited very gradual SCO behavior and changes in the dielectric constant. This shows a way in which SCO materials can be used in electronic devices.