Catalytic functionalization of low reactive C(sp3)-H and C(sp2)-H bonds of alkanes and arenes by carbene transfer from diazo compounds
Catalytic functionalization of low reactive C(sp3)-H and C(sp2)-H bonds of alkanes and arenes by carbene transfer from diazo compounds
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DOI：
10.1039/c5dt03450g
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发表时间：
2015-01-01
影响因子：
4
通讯作者：
Perez, Pedro J.
中科院分区：
文献类型：
--
作者：
Caballero, Ana;Diaz-Requejo, M. Mar;Perez, Pedro J.
The direct functionalization of low reactive C(sp(3))-H and C(sp(2))-H bonds of alkanes and arenes, respectively, by metal-induced carbene transfer from diazo compounds is reviewed. To date, this methodology has enabled the incorporation of (CRR2)-R-1 moieties from N-2=(CRR2)-R-1 in a chemo, regio, enantio or diastereoselective manner in those substrates with the appropriate selection of metal and ligands.
