Chiral 1,2,3-Triazoliums as New Cationic Organic Catalysts with Anion-Recognition Ability: Application to Asymmetric Alkylation of Oxindoles
Chiral 1,2,3-Triazoliums as New Cationic Organic Catalysts with Anion-Recognition Ability: Application to Asymmetric Alkylation of Oxindoles
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DOI：
10.1021/ja1102844
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发表时间：
2011-02-09
影响因子：
15
通讯作者：
Ooi, Takashi
中科院分区：
文献类型：
--
作者：
Ohmatsu, Kohsuke;Kiyokawa, Mari;Ooi, Takashi
设计了手性1，2，3-三氮唑类化合物，并利用其独特的阴离子结合能力对其进行了合理的结构修饰，从而建立了3-取代羟吲哚的高对映选择性烷基化反应。
Chiral 1,2,3-triazoliums have been designed, and the rational structural modification based on their unique anion-binding abilities has led to the establishment of the highly enantioselective alkylation of 3-substituted oxindoles.